SAV-ON SUPPLIES ~JANITORIAL SUPPLIES & PAPER PRODUCTS~
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MATERIAL SAFETY DATA SHEET

Product number 050

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1. Product and Company Identification

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Product name Gleme Glass Cleaner

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Effective date 01-Dec-2008

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Company information Claire Manufacturing Co.

500 Vista Ave.

Addison, IL 60101 United States

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Company phone General Assistance 630-543-7600

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Emergency telephone US 800-424-9300

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Emergency telephone outside US 703-527-3887

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Version # 12

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Supersedes date 18-Jul-2008

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Emergency overview CONTENTS UNDER PRESSURE. Aerosol. Pressurized container may explode when

exposed to heat or flame. May be ignited by heat, sparks or flames. Prolonged exposure

may cause chronic effects.

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2. Hazards Identification

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Eyes Health injuries are not known or expected under normal use.

Potential health effects

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Skin This product may be harmful if it is absorbed through the skin. Prolonged or repeated

contact can result in defatting and drying of the skin which may result in skin irritation and

dermatitis (rash).

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Inhalation Intentional misuse by concentrating and inhaling the product can be harmful or fatal.

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Ingestion Exposure by ingestion of an aerosol is unlikely. Ingestion may cause gastrointestinal

irritation, nausea, vomiting and diarrhea.

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Target organs Kidney.

2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is

repeated and prolonged and may cause blood damage. These effects have not been

observed in humans.

Blood. Central nervous system. Liver. Respiratory system.

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Chronic effects Unconsciousness. Liver injury may occur. Kidney injury may occur.

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CAS # Percent

111-76-2 3 - 5

Components

2-Butoxyethanol

Ethyl Alcohol 64-17-5 3 - 5

Propane 74-98-6 1 - 3

n-Butane 106-97-8 1 - 3

Non-hazardous and other components below reportable levels 80 - 90

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3. Composition / Information on Ingredients

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Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact

lenses, if present and easy to do. Get medical attention if irritation develops or persists.

First aid procedures

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4. First Aid Measures

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Skin contact Immediately take off all contaminated clothing. Wash off with warm water and soap. Get

medical attention if irritation develops or persists.

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Inhalation Call a physician if symptoms develop or persist.

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Ingestion Rinse mouth. Do not induce vomiting without medical advice. If vomiting occurs naturally,

have victim lean forward to reduce risk of aspiration.

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trade_name

Product #: 050 Revision date: 01-DEC-2008 Print date: 01-DEC-2008

MSDS US

1 / 5

Gleme Glass Cleaner

Claire Manufacturing

500 Vista Ave.

Addison, IL 60101 United States

Gleme Glass Cleaner

Suitable extinguishing media Large Fires: Water spray, fog or regular foam.

Small Fires: Dry chemical, CO2, water spray or regular foam.

Extinguishing media

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5. Fire Fighting Measures

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Protective equipment and

precautions for firefighters

Wear full protective clothing, including helmet, self-contained positive pressure or

pressure demand breathing apparatus, protective clothing and face mask. Containers

should be cooled with water to prevent vapor pressure build up. Do not scatter spilled

material with high pressure water streams.

Protection of firefighters

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Methods for containment Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).

Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the

leak is irreparable.

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6. Accidental Release Measures

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Methods for cleaning up Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated

surface thoroughly.

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Handling Pressurized container: Do not pierce or burn, even after use. Do not handle or store near

an open flame, heat or other sources of ignition. Do not use if spray button is missing or

defective. Use only with adequate ventilation. Do not get this material in contact with

eyes. Do not get this material in contact with skin. Avoid prolonged exposure.

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7. Handling and Storage

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Storage Level 1 Aerosol.

Contents under pressure. Do not puncture, incinerate or crush. Avoid exposure to long

periods of sunlight. Keep out of the reach of children.

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Exposure limits

ACGIH

Components CAS #

2-Butoxyethanol 111-76-2

TWA

20 ppm

STEL

Not established

Ceiling

Not established

Ethyl Alcohol 64-17-5 1000 ppm Not established Not established

Propane 74-98-6 1000 ppm Not established Not established

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n-Butane 106-97-8 1000 ppm Not established Not established

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8. Exposure Controls / Personal Protection

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OSHA

Components CAS #

2-Butoxyethanol 111-76-2

TWA

50 ppm

STEL

Not established

Ceiling

Not established

Ethyl Alcohol 64-17-5 1000 ppm Not established Not established

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Propane 74-98-6 1000 ppm Not established Not established

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Eye / face protection Not normally needed.

Personal protective equipment

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Skin protection Protective gloves.

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Respiratory protection When workers are facing concentrations above the exposure limit they must use

appropriate certified respirators.

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Appearance Compressed liquefied gas.

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9. Physical & Chemical Properties

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Boiling point 206.6 °F (97.2 °C) estimated

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Color Colorless.

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Flammability (HOC) 3.83 kJ/g

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Flash back No

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Flash point None

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Form Aerosol.

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trade_name

Product #: 050 Revision date: 01-DEC-2008 Print date: 01-DEC-2008

MSDS US

Gleme Glass Cleaner 2 / 5

Odor Butyl

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pH 9.5 - 10.5

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Physical state Liquid.

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Pressure 70 - 90 psig @ 70F

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Solubility Completely

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Specific gravity 0.9888 estimated

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Chemical stability Stable at normal conditions.

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10. Chemical Stability & Reactivity Information

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Conditions to avoid Heat, flames and sparks.

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Incompatible materials None known.

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Hazardous decomposition products May include oxides of nitrogen.

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Acute effects Acute LD50: 5699 mg/kg estimated, Rat, Dermal

Acute LC50: 56 mg/l/4h estimated, Rat, Inhalation

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11. Toxicological Information

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Sensitization Not expected to be hazardous by OSHA criteria.

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Reproductive effects Not expected to be hazardous by OSHA criteria. Possible reproductive hazard.

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Teratogenicity Not expected to be hazardous by OSHA criteria.

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Ecotoxicity LC50 28957 mg/L estimated, Fish, 96.00 Hours,

EC50 43419 mg/L estimated, Daphnia, 48.00 Hours,

IC50 12207 mg/L estimated, Algae, 72.00 Hours,

Components of this product have been identified as having potential environmental

concerns.

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12. Ecological Information

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Waste codes D001: Waste Flammable material with a flash point <140 F

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13. Disposal Considerations

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Disposal instructions Contents under pressure. Dispose of this material and its container at hazardous or

special waste collection point. Do not allow this material to drain into sewers/water

supplies. If discarded, this product is considered a RCRA ignitable waste, D001. Dispose

in accordance with all applicable regulations.

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Department of Transportation (DOT) Requirements

Consumer commodity

ORM-D

None

Hazard class

Subsidiary hazard class

Proper shipping name

Basic shipping requirements:

156, 306

156, 306

None

Packaging exceptions

Packaging non bulk

Packaging bulk

Additional information:

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14. Transport Information

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IMDG

AEROSOLS

2.1

1950

Hazard class

UN number

Proper shipping name

Basic shipping requirements:

LTD QTY

5F

None

2

Packaging exceptions

Item

Labels required

Transport Category

Additional information:

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trade_name

Product #: 050 Revision date: 01-DEC-2008 Print date: 01-DEC-2008

MSDS US

Gleme Glass Cleaner 3 / 5

IATA

Aerosols, flammable

2.1

1950

Hazard class

UN number

Proper shipping name

Basic shipping requirements:

LTD QTY

2.1

Packaging exceptions

Labels required

Additional information:

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US federal regulations

U.S. - CERCLA/SARA - Section 313 - Emission Reporting

111-76-2 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3,

R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or

less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or

sulfonate, Chemical Category N230)

2-Butoxyethanol

This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication

Standard, 29 CFR 1910.1200.

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15. Regulatory Information

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29 CFR 1910.1200 hazardous

chemical

Yes

Occupational Safety and Health Administration (OSHA)

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None

CERCLA (Superfund) reportable quantity

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Hazard categories Immediate Hazard - Yes

Delayed Hazard - Yes

Fire Hazard - No

Pressure Hazard - Yes

Reactivity Hazard - No

Superfund Amendments and Reauthorization Act of 1986 (SARA)

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Section 302 extremely

hazardous substance

No

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Section 311 hazardous chemical Yes

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Inventory status

Country(s) or region Inventory name On inventory (yes/no)*

No

Yes

Yes

No

No

China

Europe

Europe

Japan

Korea

Inventory of Existing Chemical Substances in China (IECSC)

European Inventory of New and Existing Chemicals (EINECS)

European List of Notified Chemical Substances (ELINCS)

Inventory of Existing and New Chemical Substances (ENCS)

Existing Chemicals List (ECL)

Yes

A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)

United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory

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State regulations

U.S. - Pennsylvania - RTK (Right to Know) List

2-Butoxyethanol 111-76-2 Present

Ethyl Alcohol 64-17-5 Present

n-Butane 106-97-8 Present

Propane 74-98-6 Present

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HMIS® ratings Health: 1

Flammability: 1

Physical hazard: 0

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16. Other Information

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Disclaimer The information provided in this Safety Data Sheet is correct to the best of our

knowledge, information and belief at the date of its publication. The information given is

designed only as a guidance for safe handling, use, processing, storage, transportation,

disposal and release and is not to be considered a warranty or quality specification. The

information relates only to the specific material designated and may not be valid for such

material used in combination with any other materials or in any process, unless specified

in the text.

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trade_name

Product #: 050 Revision date: 01-DEC-2008 Print date: 01-DEC-2008

MSDS US

Gleme Glass Cleaner 4 / 5

MSDS sections updated Product and Company Identification: Alternate Trade Names

Physical & Chemical Properties: Physical & Chemical Properties

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trade_name

Product #: 050 Revision date: 01-DEC-2008 Print date: 01-DEC-2008

MSDS US

Gleme Glass Cleaner 5 / 5

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